diff --git a/TOC_Analysis/20260909/IC_Calibration.cal b/TOC_Analysis/20260909/IC_Calibration.cal index 516fc3d..ccf7eca 100644 --- a/TOC_Analysis/20260909/IC_Calibration.cal +++ b/TOC_Analysis/20260909/IC_Calibration.cal @@ -24,4 +24,4 @@ R2 0.9327 EXCLUDED None FROM 0.0500 TO 2.0000 -COMPUTED 11.09.2026 16:48:19 \ No newline at end of file +COMPUTED 11.09.2026 17:35:49 \ No newline at end of file diff --git a/TOC_Analysis/20260909/IC_Calibration_11_09_2026_17_45_52.cal b/TOC_Analysis/20260909/IC_Calibration_11_09_2026_17_45_52.cal new file mode 100644 index 0000000..ceb614c --- /dev/null +++ b/TOC_Analysis/20260909/IC_Calibration_11_09_2026_17_45_52.cal @@ -0,0 +1,27 @@ +METADATA +---------------------------------------------------------------------- +Standard 2.00 +Unit mg/L +Prepared 10.06.2026 +Measured 10.09.2026 + +CALIBRATION DATA +conc. STD Dilution A1 A2 A3 +(mg / L) (-) (-) (-) (-) +0.05 40.00 0.4019 0.9061 0.6915 +0.10 20.00 1.264 1.230 1.249 +0.20 10.00 1.909 2.049 2.005 +0.50 4.000 5.410 5.482 5.887 +0.70 2.857 7.544 8.078 7.808 +1.00 2.000 10.83 10.76 10.53 +2.00 1.000 21.69 21.67 0.03210 + +CALIBRATION RESULTS +---------------------------------------------------------------------- +Slope 0.0928 +Intercept -0.0084 +R2 0.9983 +EXCLUDED 7 +FROM 0.0500 +TO 1.0000 +COMPUTED 11.09.2026 17:45:52 \ No newline at end of file diff --git a/TOC_Analysis/20260909/analysis.ipynb b/TOC_Analysis/20260909/analysis.ipynb index a24d0d3..5386582 100644 --- a/TOC_Analysis/20260909/analysis.ipynb +++ b/TOC_Analysis/20260909/analysis.ipynb @@ -2,7 +2,7 @@ "cells": [ { "cell_type": "code", - "execution_count": 4, + "execution_count": 1, "id": "393a8a7f", "metadata": {}, "outputs": [], @@ -22,7 +22,7 @@ }, { "cell_type": "code", - "execution_count": 5, + "execution_count": 19, "id": "3151288f", "metadata": {}, "outputs": [], @@ -35,7 +35,7 @@ " 'font.serif': [],\n", " 'font.sans-serif': [],\n", " 'font.size': 8,\n", - " 'legend.fontsize': 8,\n", + " 'legend.fontsize': 6,\n", " 'xtick.labelsize': 8,\n", " 'ytick.labelsize': 8,\n", " 'pgf.texsystem': r'lualatex',\n", @@ -53,24 +53,10 @@ }, { "cell_type": "code", - "execution_count": 7, + "execution_count": 3, "id": "ea0c4325", "metadata": {}, "outputs": [ - { - "name": "stdout", - "output_type": "stream", - "text": [ - " concentration dilution area_1 area_2 area_3 area_average\n", - "0 0.05 40.000 0.4019 0.9061 0.6915 0.666500\n", - "1 0.10 20.000 1.2640 1.2300 1.2490 1.247667\n", - "2 0.20 10.000 1.9090 2.0490 2.0050 1.987667\n", - "3 0.50 4.000 5.4100 5.4820 5.8870 5.593000\n", - "4 0.70 2.857 7.5440 8.0780 7.8080 7.810000\n", - "5 1.00 2.000 10.8300 10.7600 10.5300 10.706667\n", - "6 2.00 1.000 21.6900 21.6700 0.0321 14.464033\n" - ] - }, { "name": "stderr", "output_type": "stream", @@ -81,15 +67,14 @@ } ], "source": [ - "calibration = Calibration(cal_file = Path(r\"C:\\Users\\tschan_d\\Documents\\analysis\\TOC_Analysis\\20260909\\IC_Calibration.cal\"))\n", - "calibration.calibrate()\n", - "\n", - "print(calibration.calibrant_data)" + "cal_01 = Calibration(cal_file = Path(r\"C:\\Users\\tschan_d\\Documents\\analysis\\TOC_Analysis\\20260909\\IC_Calibration.cal\"))\n", + "cal_02 = Calibration(cal_file = Path(r\"C:\\Users\\tschan_d\\Documents\\analysis\\TOC_Analysis\\20260909\\IC_Calibration.cal\"))\n", + "cal_02.calibrate(excluded_points=[7], write_to_new_file=True)" ] }, { "cell_type": "code", - "execution_count": 14, + "execution_count": 42, "id": "00b59d82", "metadata": {}, "outputs": [], @@ -99,21 +84,33 @@ "fig = plt.figure(figsize=(8.8 / 2.54, 5 / 2.54))\n", "ax_1 = plt.axes([0.2, 0.2, 0.6, 0.6], frameon=True)\n", "\n", - "ax_1.plot(calibration.calibrant_data['area_average'], calibration.calibrant_data['concentration'], color = 'red',\n", - " linestyle = 'None',\n", - " marker = 'o',\n", - " markersize = 2.5,\n", - " markerfacecolor = 'red')\n", + "# calibration curve with outliers\n", + "ax_1.scatter(cal_01.calibrant_data['area_average'],\n", + " cal_01.calibrant_data['concentration'],\n", + " color = 'red',\n", + " marker = 'o',\n", + " s = 10,\n", + " facecolor = 'None',\n", + " edgecolor = 'red',\n", + " linewidth = 0.75)\n", + "ax_1.plot([0, 17], cal_01.compute([0, 17]), linestyle = '--', color = 'red', linewidth = 0.75, label = f\"$c={cal_01.curve.slope:1.2f}A-{abs(cal_01.curve.intercept):1.2f},\\,\" + r'\\textnormal{R}^{2}=' + f\"{cal_01.curve.R2_value:1.3f}$\")\n", "\n", - "ax_1.plot([0, 17], calibration.compute([0, 17]), 'k')\n", - "\n", - "ax_1.set_xlabel(r'Area $(-)$')\n", - "ax_1.set_ylabel(r'Concentration $(\\unit{\\milli\\gram\\per\\liter})$')\n", + "# calibration curve without outliers\n", + "ax_1.scatter(cal_02.calibrant_data['area_average'][cal_02.mask],\n", + " cal_02.calibrant_data['concentration'][cal_02.mask],\n", + " color = 'black',\n", + " marker = '.',\n", + " s = 5,\n", + " facecolor = 'black')\n", + "ax_1.plot([0, 17], cal_02.compute([0, 17]), linestyle = '-', color = 'black', linewidth = 0.75, label = f\"$c={cal_02.curve.slope:1.2f}A-{abs(cal_02.curve.intercept):1.2f},\\,\" + r'\\textnormal{R}^{2}=' + f\"{cal_02.curve.R2_value:1.3f}$\")\n", + "ax_1.set_xlabel(r'Area $A$ $(-)$')\n", + "ax_1.set_ylabel(r'Concentration $c$ $(\\unit{\\milli\\gram\\per\\liter})$')\n", "\n", "ax_1.set_xlim([0, 16])\n", "ax_1.set_ylim([0, 2.1])\n", "\n", "lines_1, labels_1 = ax_1.get_legend_handles_labels()\n", + "ax_1.legend(loc = 'upper left', handlelength = 1, borderpad = 0.7)\n", "\n", "#plt.show()\n", "plt.savefig(\"figure.pgf\", format='pgf', dpi=400)\n", diff --git a/TOC_Analysis/20260909/figure.pgf b/TOC_Analysis/20260909/figure.pgf index 7ce7011..0db6f85 100644 --- a/TOC_Analysis/20260909/figure.pgf +++ b/TOC_Analysis/20260909/figure.pgf @@ -71,6 +71,210 @@ \pgfusepath{fill}% \end{pgfscope}% \begin{pgfscope}% +\pgfpathrectangle{\pgfqpoint{0.692913in}{0.393701in}}{\pgfqpoint{2.078740in}{1.181102in}}% +\pgfusepath{clip}% +\pgfsetbuttcap% +\pgfsetroundjoin% +\pgfsetlinewidth{0.752812pt}% +\definecolor{currentstroke}{rgb}{1.000000,0.000000,0.000000}% +\pgfsetstrokecolor{currentstroke}% +\pgfsetdash{}{0pt}% +\pgfpathmoveto{\pgfqpoint{0.779506in}{0.399862in}}% +\pgfpathcurveto{\pgfqpoint{0.785330in}{0.399862in}}{\pgfqpoint{0.790916in}{0.402176in}}{\pgfqpoint{0.795034in}{0.406294in}}% +\pgfpathcurveto{\pgfqpoint{0.799152in}{0.410412in}}{\pgfqpoint{0.801466in}{0.415998in}}{\pgfqpoint{0.801466in}{0.421822in}}% +\pgfpathcurveto{\pgfqpoint{0.801466in}{0.427646in}}{\pgfqpoint{0.799152in}{0.433232in}}{\pgfqpoint{0.795034in}{0.437351in}}% +\pgfpathcurveto{\pgfqpoint{0.790916in}{0.441469in}}{\pgfqpoint{0.785330in}{0.443783in}}{\pgfqpoint{0.779506in}{0.443783in}}% +\pgfpathcurveto{\pgfqpoint{0.773682in}{0.443783in}}{\pgfqpoint{0.768096in}{0.441469in}}{\pgfqpoint{0.763978in}{0.437351in}}% +\pgfpathcurveto{\pgfqpoint{0.759860in}{0.433232in}}{\pgfqpoint{0.757546in}{0.427646in}}{\pgfqpoint{0.757546in}{0.421822in}}% +\pgfpathcurveto{\pgfqpoint{0.757546in}{0.415998in}}{\pgfqpoint{0.759860in}{0.410412in}}{\pgfqpoint{0.763978in}{0.406294in}}% +\pgfpathcurveto{\pgfqpoint{0.768096in}{0.402176in}}{\pgfqpoint{0.773682in}{0.399862in}}{\pgfqpoint{0.779506in}{0.399862in}}% +\pgfpathlineto{\pgfqpoint{0.779506in}{0.399862in}}% +\pgfpathclose% +\pgfusepath{stroke}% +\end{pgfscope}% +\begin{pgfscope}% +\pgfpathrectangle{\pgfqpoint{0.692913in}{0.393701in}}{\pgfqpoint{2.078740in}{1.181102in}}% +\pgfusepath{clip}% +\pgfsetbuttcap% +\pgfsetroundjoin% +\pgfsetlinewidth{0.752812pt}% +\definecolor{currentstroke}{rgb}{1.000000,0.000000,0.000000}% +\pgfsetstrokecolor{currentstroke}% +\pgfsetdash{}{0pt}% +\pgfpathmoveto{\pgfqpoint{0.855012in}{0.427983in}}% +\pgfpathcurveto{\pgfqpoint{0.860836in}{0.427983in}}{\pgfqpoint{0.866422in}{0.430297in}}{\pgfqpoint{0.870540in}{0.434416in}}% +\pgfpathcurveto{\pgfqpoint{0.874658in}{0.438534in}}{\pgfqpoint{0.876972in}{0.444120in}}{\pgfqpoint{0.876972in}{0.449944in}}% +\pgfpathcurveto{\pgfqpoint{0.876972in}{0.455768in}}{\pgfqpoint{0.874658in}{0.461354in}}{\pgfqpoint{0.870540in}{0.465472in}}% +\pgfpathcurveto{\pgfqpoint{0.866422in}{0.469590in}}{\pgfqpoint{0.860836in}{0.471904in}}{\pgfqpoint{0.855012in}{0.471904in}}% +\pgfpathcurveto{\pgfqpoint{0.849188in}{0.471904in}}{\pgfqpoint{0.843602in}{0.469590in}}{\pgfqpoint{0.839484in}{0.465472in}}% +\pgfpathcurveto{\pgfqpoint{0.835365in}{0.461354in}}{\pgfqpoint{0.833052in}{0.455768in}}{\pgfqpoint{0.833052in}{0.449944in}}% +\pgfpathcurveto{\pgfqpoint{0.833052in}{0.444120in}}{\pgfqpoint{0.835365in}{0.438534in}}{\pgfqpoint{0.839484in}{0.434416in}}% +\pgfpathcurveto{\pgfqpoint{0.843602in}{0.430297in}}{\pgfqpoint{0.849188in}{0.427983in}}{\pgfqpoint{0.855012in}{0.427983in}}% +\pgfpathlineto{\pgfqpoint{0.855012in}{0.427983in}}% +\pgfpathclose% +\pgfusepath{stroke}% +\end{pgfscope}% +\begin{pgfscope}% +\pgfpathrectangle{\pgfqpoint{0.692913in}{0.393701in}}{\pgfqpoint{2.078740in}{1.181102in}}% +\pgfusepath{clip}% +\pgfsetbuttcap% +\pgfsetroundjoin% +\pgfsetlinewidth{0.752812pt}% +\definecolor{currentstroke}{rgb}{1.000000,0.000000,0.000000}% +\pgfsetstrokecolor{currentstroke}% +\pgfsetdash{}{0pt}% +\pgfpathmoveto{\pgfqpoint{0.951154in}{0.484226in}}% +\pgfpathcurveto{\pgfqpoint{0.956977in}{0.484226in}}{\pgfqpoint{0.962564in}{0.486540in}}{\pgfqpoint{0.966682in}{0.490658in}}% +\pgfpathcurveto{\pgfqpoint{0.970800in}{0.494777in}}{\pgfqpoint{0.973114in}{0.500363in}}{\pgfqpoint{0.973114in}{0.506187in}}% +\pgfpathcurveto{\pgfqpoint{0.973114in}{0.512011in}}{\pgfqpoint{0.970800in}{0.517597in}}{\pgfqpoint{0.966682in}{0.521715in}}% +\pgfpathcurveto{\pgfqpoint{0.962564in}{0.525833in}}{\pgfqpoint{0.956977in}{0.528147in}}{\pgfqpoint{0.951154in}{0.528147in}}% +\pgfpathcurveto{\pgfqpoint{0.945330in}{0.528147in}}{\pgfqpoint{0.939743in}{0.525833in}}{\pgfqpoint{0.935625in}{0.521715in}}% +\pgfpathcurveto{\pgfqpoint{0.931507in}{0.517597in}}{\pgfqpoint{0.929193in}{0.512011in}}{\pgfqpoint{0.929193in}{0.506187in}}% +\pgfpathcurveto{\pgfqpoint{0.929193in}{0.500363in}}{\pgfqpoint{0.931507in}{0.494777in}}{\pgfqpoint{0.935625in}{0.490658in}}% +\pgfpathcurveto{\pgfqpoint{0.939743in}{0.486540in}}{\pgfqpoint{0.945330in}{0.484226in}}{\pgfqpoint{0.951154in}{0.484226in}}% +\pgfpathlineto{\pgfqpoint{0.951154in}{0.484226in}}% +\pgfpathclose% +\pgfusepath{stroke}% +\end{pgfscope}% +\begin{pgfscope}% +\pgfpathrectangle{\pgfqpoint{0.692913in}{0.393701in}}{\pgfqpoint{2.078740in}{1.181102in}}% +\pgfusepath{clip}% +\pgfsetbuttcap% +\pgfsetroundjoin% +\pgfsetlinewidth{0.752812pt}% +\definecolor{currentstroke}{rgb}{1.000000,0.000000,0.000000}% +\pgfsetstrokecolor{currentstroke}% +\pgfsetdash{}{0pt}% +\pgfpathmoveto{\pgfqpoint{1.419563in}{0.652955in}}% +\pgfpathcurveto{\pgfqpoint{1.425387in}{0.652955in}}{\pgfqpoint{1.430973in}{0.655269in}}{\pgfqpoint{1.435091in}{0.659387in}}% +\pgfpathcurveto{\pgfqpoint{1.439209in}{0.663506in}}{\pgfqpoint{1.441523in}{0.669092in}}{\pgfqpoint{1.441523in}{0.674916in}}% +\pgfpathcurveto{\pgfqpoint{1.441523in}{0.680740in}}{\pgfqpoint{1.439209in}{0.686326in}}{\pgfqpoint{1.435091in}{0.690444in}}% +\pgfpathcurveto{\pgfqpoint{1.430973in}{0.694562in}}{\pgfqpoint{1.425387in}{0.696876in}}{\pgfqpoint{1.419563in}{0.696876in}}% +\pgfpathcurveto{\pgfqpoint{1.413739in}{0.696876in}}{\pgfqpoint{1.408153in}{0.694562in}}{\pgfqpoint{1.404035in}{0.690444in}}% +\pgfpathcurveto{\pgfqpoint{1.399917in}{0.686326in}}{\pgfqpoint{1.397603in}{0.680740in}}{\pgfqpoint{1.397603in}{0.674916in}}% +\pgfpathcurveto{\pgfqpoint{1.397603in}{0.669092in}}{\pgfqpoint{1.399917in}{0.663506in}}{\pgfqpoint{1.404035in}{0.659387in}}% +\pgfpathcurveto{\pgfqpoint{1.408153in}{0.655269in}}{\pgfqpoint{1.413739in}{0.652955in}}{\pgfqpoint{1.419563in}{0.652955in}}% +\pgfpathlineto{\pgfqpoint{1.419563in}{0.652955in}}% +\pgfpathclose% +\pgfusepath{stroke}% +\end{pgfscope}% +\begin{pgfscope}% +\pgfpathrectangle{\pgfqpoint{0.692913in}{0.393701in}}{\pgfqpoint{2.078740in}{1.181102in}}% +\pgfusepath{clip}% +\pgfsetbuttcap% +\pgfsetroundjoin% +\pgfsetlinewidth{0.752812pt}% +\definecolor{currentstroke}{rgb}{1.000000,0.000000,0.000000}% +\pgfsetstrokecolor{currentstroke}% +\pgfsetdash{}{0pt}% +\pgfpathmoveto{\pgfqpoint{1.707598in}{0.765441in}}% +\pgfpathcurveto{\pgfqpoint{1.713422in}{0.765441in}}{\pgfqpoint{1.719009in}{0.767755in}}{\pgfqpoint{1.723127in}{0.771873in}}% +\pgfpathcurveto{\pgfqpoint{1.727245in}{0.775991in}}{\pgfqpoint{1.729559in}{0.781578in}}{\pgfqpoint{1.729559in}{0.787402in}}% +\pgfpathcurveto{\pgfqpoint{1.729559in}{0.793226in}}{\pgfqpoint{1.727245in}{0.798812in}}{\pgfqpoint{1.723127in}{0.802930in}}% +\pgfpathcurveto{\pgfqpoint{1.719009in}{0.807048in}}{\pgfqpoint{1.713422in}{0.809362in}}{\pgfqpoint{1.707598in}{0.809362in}}% +\pgfpathcurveto{\pgfqpoint{1.701774in}{0.809362in}}{\pgfqpoint{1.696188in}{0.807048in}}{\pgfqpoint{1.692070in}{0.802930in}}% +\pgfpathcurveto{\pgfqpoint{1.687952in}{0.798812in}}{\pgfqpoint{1.685638in}{0.793226in}}{\pgfqpoint{1.685638in}{0.787402in}}% +\pgfpathcurveto{\pgfqpoint{1.685638in}{0.781578in}}{\pgfqpoint{1.687952in}{0.775991in}}{\pgfqpoint{1.692070in}{0.771873in}}% +\pgfpathcurveto{\pgfqpoint{1.696188in}{0.767755in}}{\pgfqpoint{1.701774in}{0.765441in}}{\pgfqpoint{1.707598in}{0.765441in}}% +\pgfpathlineto{\pgfqpoint{1.707598in}{0.765441in}}% +\pgfpathclose% +\pgfusepath{stroke}% +\end{pgfscope}% +\begin{pgfscope}% +\pgfpathrectangle{\pgfqpoint{0.692913in}{0.393701in}}{\pgfqpoint{2.078740in}{1.181102in}}% +\pgfusepath{clip}% +\pgfsetbuttcap% +\pgfsetroundjoin% +\pgfsetlinewidth{0.752812pt}% +\definecolor{currentstroke}{rgb}{1.000000,0.000000,0.000000}% +\pgfsetstrokecolor{currentstroke}% +\pgfsetdash{}{0pt}% +\pgfpathmoveto{\pgfqpoint{2.083937in}{0.934170in}}% +\pgfpathcurveto{\pgfqpoint{2.089761in}{0.934170in}}{\pgfqpoint{2.095347in}{0.936484in}}{\pgfqpoint{2.099465in}{0.940602in}}% +\pgfpathcurveto{\pgfqpoint{2.103583in}{0.944720in}}{\pgfqpoint{2.105897in}{0.950307in}}{\pgfqpoint{2.105897in}{0.956130in}}% +\pgfpathcurveto{\pgfqpoint{2.105897in}{0.961954in}}{\pgfqpoint{2.103583in}{0.967541in}}{\pgfqpoint{2.099465in}{0.971659in}}% +\pgfpathcurveto{\pgfqpoint{2.095347in}{0.975777in}}{\pgfqpoint{2.089761in}{0.978091in}}{\pgfqpoint{2.083937in}{0.978091in}}% +\pgfpathcurveto{\pgfqpoint{2.078113in}{0.978091in}}{\pgfqpoint{2.072527in}{0.975777in}}{\pgfqpoint{2.068409in}{0.971659in}}% +\pgfpathcurveto{\pgfqpoint{2.064291in}{0.967541in}}{\pgfqpoint{2.061977in}{0.961954in}}{\pgfqpoint{2.061977in}{0.956130in}}% +\pgfpathcurveto{\pgfqpoint{2.061977in}{0.950307in}}{\pgfqpoint{2.064291in}{0.944720in}}{\pgfqpoint{2.068409in}{0.940602in}}% +\pgfpathcurveto{\pgfqpoint{2.072527in}{0.936484in}}{\pgfqpoint{2.078113in}{0.934170in}}{\pgfqpoint{2.083937in}{0.934170in}}% +\pgfpathlineto{\pgfqpoint{2.083937in}{0.934170in}}% +\pgfpathclose% +\pgfusepath{stroke}% +\end{pgfscope}% +\begin{pgfscope}% +\pgfpathrectangle{\pgfqpoint{0.692913in}{0.393701in}}{\pgfqpoint{2.078740in}{1.181102in}}% +\pgfusepath{clip}% +\pgfsetbuttcap% +\pgfsetroundjoin% +\pgfsetlinewidth{0.752812pt}% +\definecolor{currentstroke}{rgb}{1.000000,0.000000,0.000000}% +\pgfsetstrokecolor{currentstroke}% +\pgfsetdash{}{0pt}% +\pgfpathmoveto{\pgfqpoint{2.572099in}{1.496600in}}% +\pgfpathcurveto{\pgfqpoint{2.577923in}{1.496600in}}{\pgfqpoint{2.583509in}{1.498914in}}{\pgfqpoint{2.587627in}{1.503032in}}% +\pgfpathcurveto{\pgfqpoint{2.591745in}{1.507150in}}{\pgfqpoint{2.594059in}{1.512736in}}{\pgfqpoint{2.594059in}{1.518560in}}% +\pgfpathcurveto{\pgfqpoint{2.594059in}{1.524384in}}{\pgfqpoint{2.591745in}{1.529970in}}{\pgfqpoint{2.587627in}{1.534088in}}% +\pgfpathcurveto{\pgfqpoint{2.583509in}{1.538207in}}{\pgfqpoint{2.577923in}{1.540520in}}{\pgfqpoint{2.572099in}{1.540520in}}% +\pgfpathcurveto{\pgfqpoint{2.566275in}{1.540520in}}{\pgfqpoint{2.560689in}{1.538207in}}{\pgfqpoint{2.556571in}{1.534088in}}% +\pgfpathcurveto{\pgfqpoint{2.552452in}{1.529970in}}{\pgfqpoint{2.550139in}{1.524384in}}{\pgfqpoint{2.550139in}{1.518560in}}% +\pgfpathcurveto{\pgfqpoint{2.550139in}{1.512736in}}{\pgfqpoint{2.552452in}{1.507150in}}{\pgfqpoint{2.556571in}{1.503032in}}% +\pgfpathcurveto{\pgfqpoint{2.560689in}{1.498914in}}{\pgfqpoint{2.566275in}{1.496600in}}{\pgfqpoint{2.572099in}{1.496600in}}% +\pgfpathlineto{\pgfqpoint{2.572099in}{1.496600in}}% +\pgfpathclose% +\pgfusepath{stroke}% +\end{pgfscope}% +\begin{pgfscope}% +\pgfpathrectangle{\pgfqpoint{0.692913in}{0.393701in}}{\pgfqpoint{2.078740in}{1.181102in}}% +\pgfusepath{clip}% +\pgfsetbuttcap% +\pgfsetroundjoin% +\definecolor{currentfill}{rgb}{0.000000,0.000000,0.000000}% +\pgfsetfillcolor{currentfill}% +\pgfsetlinewidth{0.602250pt}% +\definecolor{currentstroke}{rgb}{0.000000,0.000000,0.000000}% +\pgfsetstrokecolor{currentstroke}% +\pgfsetdash{}{0pt}% +\pgfsys@defobject{currentmarker}{\pgfqpoint{-0.007764in}{-0.007764in}}{\pgfqpoint{0.007764in}{0.007764in}}{% +\pgfpathmoveto{\pgfqpoint{0.000000in}{-0.007764in}}% +\pgfpathcurveto{\pgfqpoint{0.002059in}{-0.007764in}}{\pgfqpoint{0.004034in}{-0.006946in}}{\pgfqpoint{0.005490in}{-0.005490in}}% +\pgfpathcurveto{\pgfqpoint{0.006946in}{-0.004034in}}{\pgfqpoint{0.007764in}{-0.002059in}}{\pgfqpoint{0.007764in}{0.000000in}}% +\pgfpathcurveto{\pgfqpoint{0.007764in}{0.002059in}}{\pgfqpoint{0.006946in}{0.004034in}}{\pgfqpoint{0.005490in}{0.005490in}}% +\pgfpathcurveto{\pgfqpoint{0.004034in}{0.006946in}}{\pgfqpoint{0.002059in}{0.007764in}}{\pgfqpoint{0.000000in}{0.007764in}}% +\pgfpathcurveto{\pgfqpoint{-0.002059in}{0.007764in}}{\pgfqpoint{-0.004034in}{0.006946in}}{\pgfqpoint{-0.005490in}{0.005490in}}% +\pgfpathcurveto{\pgfqpoint{-0.006946in}{0.004034in}}{\pgfqpoint{-0.007764in}{0.002059in}}{\pgfqpoint{-0.007764in}{0.000000in}}% +\pgfpathcurveto{\pgfqpoint{-0.007764in}{-0.002059in}}{\pgfqpoint{-0.006946in}{-0.004034in}}{\pgfqpoint{-0.005490in}{-0.005490in}}% +\pgfpathcurveto{\pgfqpoint{-0.004034in}{-0.006946in}}{\pgfqpoint{-0.002059in}{-0.007764in}}{\pgfqpoint{0.000000in}{-0.007764in}}% +\pgfpathlineto{\pgfqpoint{0.000000in}{-0.007764in}}% +\pgfpathclose% +\pgfusepath{stroke,fill}% +}% +\begin{pgfscope}% +\pgfsys@transformshift{0.779506in}{0.421822in}% +\pgfsys@useobject{currentmarker}{}% +\end{pgfscope}% +\begin{pgfscope}% +\pgfsys@transformshift{0.855012in}{0.449944in}% +\pgfsys@useobject{currentmarker}{}% +\end{pgfscope}% +\begin{pgfscope}% +\pgfsys@transformshift{0.951154in}{0.506187in}% +\pgfsys@useobject{currentmarker}{}% +\end{pgfscope}% +\begin{pgfscope}% +\pgfsys@transformshift{1.419563in}{0.674916in}% +\pgfsys@useobject{currentmarker}{}% +\end{pgfscope}% +\begin{pgfscope}% +\pgfsys@transformshift{1.707598in}{0.787402in}% +\pgfsys@useobject{currentmarker}{}% +\end{pgfscope}% +\begin{pgfscope}% +\pgfsys@transformshift{2.083937in}{0.956130in}% +\pgfsys@useobject{currentmarker}{}% +\end{pgfscope}% +\end{pgfscope}% +\begin{pgfscope}% \pgfsetbuttcap% \pgfsetroundjoin% \definecolor{currentfill}{rgb}{0.000000,0.000000,0.000000}% @@ -744,7 +948,7 @@ \definecolor{textcolor}{rgb}{0.000000,0.000000,0.000000}% \pgfsetstrokecolor{textcolor}% \pgfsetfillcolor{textcolor}% -\pgftext[x=1.732283in,y=0.186645in,,top]{\color{textcolor}{\rmfamily\fontsize{8.000000}{9.600000}\selectfont\catcode`\^=\active\def^{\ifmmode\sp\else\^{}\fi}\catcode`\%=\active\def%{\%}Area $(-)$}}% +\pgftext[x=1.732283in,y=0.186645in,,top]{\color{textcolor}{\rmfamily\fontsize{8.000000}{9.600000}\selectfont\catcode`\^=\active\def^{\ifmmode\sp\else\^{}\fi}\catcode`\%=\active\def%{\%}Area $A$ $(-)$}}% \end{pgfscope}% \begin{pgfscope}% \pgfsetbuttcap% @@ -1616,74 +1820,32 @@ \definecolor{textcolor}{rgb}{0.000000,0.000000,0.000000}% \pgfsetstrokecolor{textcolor}% \pgfsetfillcolor{textcolor}% -\pgftext[x=0.451524in,y=0.984252in,,bottom,rotate=90.000000]{\color{textcolor}{\rmfamily\fontsize{8.000000}{9.600000}\selectfont\catcode`\^=\active\def^{\ifmmode\sp\else\^{}\fi}\catcode`\%=\active\def%{\%}Concentration $(\unit{\milli\gram\per\liter})$}}% +\pgftext[x=0.451524in,y=0.984252in,,bottom,rotate=90.000000]{\color{textcolor}{\rmfamily\fontsize{8.000000}{9.600000}\selectfont\catcode`\^=\active\def^{\ifmmode\sp\else\^{}\fi}\catcode`\%=\active\def%{\%}Concentration $c$ $(\unit{\milli\gram\per\liter})$}}% \end{pgfscope}% \begin{pgfscope}% \pgfpathrectangle{\pgfqpoint{0.692913in}{0.393701in}}{\pgfqpoint{2.078740in}{1.181102in}}% \pgfusepath{clip}% \pgfsetbuttcap% \pgfsetroundjoin% -\definecolor{currentfill}{rgb}{1.000000,0.000000,0.000000}% -\pgfsetfillcolor{currentfill}% -\pgfsetlinewidth{0.000000pt}% -\definecolor{currentstroke}{rgb}{0.000000,0.000000,0.000000}% +\pgfsetlinewidth{0.752812pt}% +\definecolor{currentstroke}{rgb}{1.000000,0.000000,0.000000}% \pgfsetstrokecolor{currentstroke}% -\pgfsetstrokeopacity{0.000000}% -\pgfsetdash{}{0pt}% -\pgfsys@defobject{currentmarker}{\pgfqpoint{-0.017361in}{-0.017361in}}{\pgfqpoint{0.017361in}{0.017361in}}{% -\pgfpathmoveto{\pgfqpoint{0.000000in}{-0.017361in}}% -\pgfpathcurveto{\pgfqpoint{0.004604in}{-0.017361in}}{\pgfqpoint{0.009020in}{-0.015532in}}{\pgfqpoint{0.012276in}{-0.012276in}}% -\pgfpathcurveto{\pgfqpoint{0.015532in}{-0.009020in}}{\pgfqpoint{0.017361in}{-0.004604in}}{\pgfqpoint{0.017361in}{0.000000in}}% -\pgfpathcurveto{\pgfqpoint{0.017361in}{0.004604in}}{\pgfqpoint{0.015532in}{0.009020in}}{\pgfqpoint{0.012276in}{0.012276in}}% -\pgfpathcurveto{\pgfqpoint{0.009020in}{0.015532in}}{\pgfqpoint{0.004604in}{0.017361in}}{\pgfqpoint{0.000000in}{0.017361in}}% -\pgfpathcurveto{\pgfqpoint{-0.004604in}{0.017361in}}{\pgfqpoint{-0.009020in}{0.015532in}}{\pgfqpoint{-0.012276in}{0.012276in}}% -\pgfpathcurveto{\pgfqpoint{-0.015532in}{0.009020in}}{\pgfqpoint{-0.017361in}{0.004604in}}{\pgfqpoint{-0.017361in}{0.000000in}}% -\pgfpathcurveto{\pgfqpoint{-0.017361in}{-0.004604in}}{\pgfqpoint{-0.015532in}{-0.009020in}}{\pgfqpoint{-0.012276in}{-0.012276in}}% -\pgfpathcurveto{\pgfqpoint{-0.009020in}{-0.015532in}}{\pgfqpoint{-0.004604in}{-0.017361in}}{\pgfqpoint{0.000000in}{-0.017361in}}% -\pgfpathlineto{\pgfqpoint{0.000000in}{-0.017361in}}% -\pgfpathclose% -\pgfusepath{fill}% -}% -\begin{pgfscope}% -\pgfsys@transformshift{0.779506in}{0.421822in}% -\pgfsys@useobject{currentmarker}{}% -\end{pgfscope}% -\begin{pgfscope}% -\pgfsys@transformshift{0.855012in}{0.449944in}% -\pgfsys@useobject{currentmarker}{}% -\end{pgfscope}% -\begin{pgfscope}% -\pgfsys@transformshift{0.951154in}{0.506187in}% -\pgfsys@useobject{currentmarker}{}% -\end{pgfscope}% -\begin{pgfscope}% -\pgfsys@transformshift{1.419563in}{0.674916in}% -\pgfsys@useobject{currentmarker}{}% -\end{pgfscope}% -\begin{pgfscope}% -\pgfsys@transformshift{1.707598in}{0.787402in}% -\pgfsys@useobject{currentmarker}{}% -\end{pgfscope}% -\begin{pgfscope}% -\pgfsys@transformshift{2.083937in}{0.956130in}% -\pgfsys@useobject{currentmarker}{}% -\end{pgfscope}% -\begin{pgfscope}% -\pgfsys@transformshift{2.572099in}{1.518560in}% -\pgfsys@useobject{currentmarker}{}% -\end{pgfscope}% +\pgfsetdash{{2.775000pt}{1.200000pt}}{0.000000pt}% +\pgfpathmoveto{\pgfqpoint{0.811005in}{0.391201in}}% +\pgfpathlineto{\pgfqpoint{2.774154in}{1.468808in}}% +\pgfusepath{stroke}% \end{pgfscope}% \begin{pgfscope}% \pgfpathrectangle{\pgfqpoint{0.692913in}{0.393701in}}{\pgfqpoint{2.078740in}{1.181102in}}% \pgfusepath{clip}% \pgfsetrectcap% \pgfsetroundjoin% -\pgfsetlinewidth{1.003750pt}% +\pgfsetlinewidth{0.752812pt}% \definecolor{currentstroke}{rgb}{0.000000,0.000000,0.000000}% \pgfsetstrokecolor{currentstroke}% \pgfsetdash{}{0pt}% -\pgfpathmoveto{\pgfqpoint{0.810954in}{0.391201in}}% -\pgfpathlineto{\pgfqpoint{2.774154in}{1.469224in}}% +\pgfpathmoveto{\pgfqpoint{0.698479in}{0.391201in}}% +\pgfpathlineto{\pgfqpoint{2.774154in}{1.225407in}}% \pgfusepath{stroke}% \end{pgfscope}% \begin{pgfscope}% @@ -1730,6 +1892,61 @@ \pgfpathlineto{\pgfqpoint{2.771654in}{1.574803in}}% \pgfusepath{stroke}% \end{pgfscope}% +\begin{pgfscope}% +\pgfsetbuttcap% +\pgfsetmiterjoin% +\definecolor{currentfill}{rgb}{1.000000,1.000000,1.000000}% +\pgfsetfillcolor{currentfill}% +\pgfsetfillopacity{0.800000}% +\pgfsetlinewidth{0.602250pt}% +\definecolor{currentstroke}{rgb}{0.000000,0.000000,0.000000}% +\pgfsetstrokecolor{currentstroke}% +\pgfsetstrokeopacity{0.800000}% +\pgfsetdash{}{0pt}% +\pgfpathmoveto{\pgfqpoint{0.809580in}{1.118776in}}% +\pgfpathlineto{\pgfqpoint{2.188124in}{1.118776in}}% +\pgfpathlineto{\pgfqpoint{2.188124in}{1.458136in}}% +\pgfpathlineto{\pgfqpoint{0.809580in}{1.458136in}}% +\pgfpathlineto{\pgfqpoint{0.809580in}{1.118776in}}% +\pgfpathclose% +\pgfusepath{stroke,fill}% +\end{pgfscope}% +\begin{pgfscope}% +\pgfsetbuttcap% +\pgfsetroundjoin% +\pgfsetlinewidth{0.752812pt}% +\definecolor{currentstroke}{rgb}{1.000000,0.000000,0.000000}% +\pgfsetstrokecolor{currentstroke}% +\pgfsetdash{{2.775000pt}{1.200000pt}}{0.000000pt}% +\pgfpathmoveto{\pgfqpoint{0.867913in}{1.352623in}}% +\pgfpathlineto{\pgfqpoint{0.909580in}{1.352623in}}% +\pgfpathlineto{\pgfqpoint{0.951247in}{1.352623in}}% +\pgfusepath{stroke}% +\end{pgfscope}% +\begin{pgfscope}% +\definecolor{textcolor}{rgb}{0.000000,0.000000,0.000000}% +\pgfsetstrokecolor{textcolor}% +\pgfsetfillcolor{textcolor}% +\pgftext[x=1.017913in,y=1.323456in,left,base]{\color{textcolor}{\rmfamily\fontsize{6.000000}{7.200000}\selectfont\catcode`\^=\active\def^{\ifmmode\sp\else\^{}\fi}\catcode`\%=\active\def%{\%}$c=0.13A-0.12,\,\textnormal{R}^{2}=0.933$}}% +\end{pgfscope}% +\begin{pgfscope}% +\pgfsetrectcap% +\pgfsetroundjoin% +\pgfsetlinewidth{0.752812pt}% +\definecolor{currentstroke}{rgb}{0.000000,0.000000,0.000000}% +\pgfsetstrokecolor{currentstroke}% +\pgfsetdash{}{0pt}% +\pgfpathmoveto{\pgfqpoint{0.867913in}{1.224609in}}% +\pgfpathlineto{\pgfqpoint{0.909580in}{1.224609in}}% +\pgfpathlineto{\pgfqpoint{0.951247in}{1.224609in}}% +\pgfusepath{stroke}% +\end{pgfscope}% +\begin{pgfscope}% +\definecolor{textcolor}{rgb}{0.000000,0.000000,0.000000}% +\pgfsetstrokecolor{textcolor}% +\pgfsetfillcolor{textcolor}% +\pgftext[x=1.017913in,y=1.195442in,left,base]{\color{textcolor}{\rmfamily\fontsize{6.000000}{7.200000}\selectfont\catcode`\^=\active\def^{\ifmmode\sp\else\^{}\fi}\catcode`\%=\active\def%{\%}$c=0.09A-0.01,\,\textnormal{R}^{2}=0.998$}}% +\end{pgfscope}% \end{pgfpicture}% \makeatother% \endgroup%